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Podmínky pro vysokou citlivost detekce a separační účinnost při separacích klastrových aniontů boru Horáková, Hana ; Grüner, Bohumír ; Vespalec, Radim The knowledge of UV-VIS spectra of investigated compounds is neccessary for the optimisation of detection sensitivity. The symmetry and narrow width of migrating zones require substantially improved dissolving power of the sample solvent and background electrolyte. Sodium borate buffer of pH 9.5 is more proper for separations of boron cluster anions in uncouted capillaries then sodium phosphate buffer of pH of 7. Decrease of mobilities of boron cluster anions with time has been found in chiral separations with .beta-CD if acetonitrile was present in background electrolyte Detailed record

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